
The basic white non-indicating silica gel doesn't. But self-indicating silica gels do. They are impregnated with moisture sensitive indicators which change colour as they adsorb moisture. For example, an orange silica gel which changes to dark green as it adsorbs moisture. The purpose of this being to indicate when the silica gel is saturated and unable to take up any more moisture (orange = dry, dark green = near exhausted in this case).
The shelf life of silica gel is between 4 and 12 months (although practical experience has shown that it can often far exceed this). The crucial factor is to keep it in a sealed environment until it is needed for use - it will, of course, adsorb moisture from any environment. Although the moisture uptake rate is not fast, small sachets can be particularly vulnerable to poor storage conditions - it is recommended that they are not left open to the atmosphere for longer than 15 minutes.
Air will always contain water vapour. At any given temperature there will be a saturation point at which no more moisture can be retained (any excess will condense). The Relative Humidity of air is the actual moisture content expressed as a percentage of this saturation content. The aim of using silica gel is to keep the Relative Humidity at levels below 50% of the saturation capacity. At these levels, corrosion and mould growth will not be promoted. Problems are often caused if the temperature drops as the saturation content of air at the new temperature becomes much lower.
Non-indicating (white) silica gel is non-toxic and non-flammable, it is very inert with a very high melting point. It is very much like sand and thus can safely be sent by any means of transport. Self-indicating (orange) silica gels (orange to green and orange to colourless) are similarly non-toxic and non-flammable. Self-indicating (blue to pink) silica gel was reclassified by the European Union and as of 01/07/2000 has been classified as a toxic material due to the heavy metal cobalt which forms part of the moisture sensitive indicator.
Self-indicating silica gels when they have become saturated can be regenerated by heating at 100 - 120°C until they return to their original colours. The heating literally drives off the adsorbed moisture. Regeneration can be carried out repeatedly, although eventually the crystals will lose their colour. When regenerating self-indicating silica gel sachets, only the minimum necessary heat should be used. This will prevent the sachet material from deteriorating. Although non-indicating silica gel can be regenerated in exactly the same way, it is not apparent when the silica gel is regenerated other than by checking its weight - it will return to its original dry weight when completely regenerated.